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Friday, September 25, 2015

A New Class of Polymer that Defies the Laws of Physics

By Frank Rovella

If you find yourself going straight for the technology section every time you get online or open a paper, then you’re not alone. There are a lot of us just waiting for the next big thing, seeking to be awed by some new technological development. The Industrial Space is fertile ground for this enterprise; just take a look at emerging materials technology.  
Unlike automation that has a level of predictability akin to a train that always runs on time; we can see it downrange, hear the tracks rumble, and watch it flash by.  However, materials technology is more like a seismic event, we know it’s coming but no one is sure when or how big it’s going to be.

An example is a recent discovery by the French physicist Ludwik Leibler, who is this year’s winner of the European Inventor Award in the category research.  Leibler along with his team at the Laboratoire Matière Molle et Chimie at ESPCI ParisTech, have developed a whole new class of plastics called Vitrimers. 


"Classified as supramolecular substances, Vitrimers are a derivative of thermoset plastics and exhibit self-repairing characteristics."

What’s really intriguing about Vitrimers is how they do what they do. To understand this, we’ll have to look at the mechanics of their most basic elements.  At the molecular level, the atoms that comprise standard thermosets maintain their crystalline structure through permanent or rigid chemical bonds, the strength of these bonds ultimately determines the characteristics of the material. Flex, friction, and thermal cycles break down these bonds resulting in weakening that leads to cracks and fractures. Once these bonds are broken, they cannot be repaired  However, the molecular bonds that makeup Vitrimers are neither permanent nor rigid; their state is more akin to a dynamic equilibrium. This means that molecular bonds are forming and breaking simultaneously. Regardless of the molecular structure, the number of bonds remains the same. This reaction is thermally activated allowing VItrimers to go from solid to liquid and back with no change in crystalline structure; this is known as a glass transition. These characteristics, in essence, are what make Vitrimers a self-repairing plastic. Testing conducted at the University of Minnesota concluded that fractured samples that were healed recovered 102% of tensile strength, 133% of the original tensile modulus value, and 67% of ultimate elongation. Vitrimers glass-like qualities, allow it to be welded like glass, meaning that if two surfaces are brought to a molten state and welded, when they solidify the molecules are aligned like a solid section, with no seam. This is similar to friction stir welding, but far more complete.

The self-repairing qualities of Vitrimers are paving the way for a number of impressive innovations, and will surely lead to many more.  One of these is in the medical industry, where Vitrimers are being used in what is being called “Organ Glue.” This is a self-healing polymer hydrogel that acts as an anti-hemorrhaging, wound-healing aqueous solution. Vitrimers have the ability to form “nanobridging”, that is a molecular bridging of tissue; it can be used in situations where stitches are impractical.

For the more mundane, however, these same self-healing properties can make a significant impact on manufactured goods. Self-repairing plastics means that products made from it will have a far longer service life. Simply put less material is required because fewer parts are needed to accommodate for wear.

Then there are the effects on recycling, Vitrimers by nature are ideal for recycling because they can be liquefied and solidified over and over. Think about all the plastic that can’t be recycled, they end up in landfills, and some of these plastics can take hundreds of years to decompose fully. Vitrimers could make plastics as recyclable as aluminum.

The concept of materials that self-repair, or do things that seem physically impossible certainly has an awe factor, but Vitrimers are just one example. NASA is currently developing materials that can self-heal after a meteor strike and even self-repairing alloys. As we move forward keep your eyes open, because there is a lot more from this came from.